When you send a Simple Mail Transfer Protocol (SMTP) mail message by using Secure Sockets Layer (SSL) with a Post Office Protocol version 3 (POP3) account, you may receive the following error message, and the mail message may remain in the Outbox:
'Sending and Receiving' reported error (0x8004210B) : 'The operation timed out waiting for a response from the sending (SMTP) server. If you continue to receive this message, contact your server administrator or Internet service provider (ISP).
Solution : Download This mentioned fix from microsoft site to solve this problem
http://support.microsoft.com/kb/307841/EN-US/
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